Taggent flakes for covert security applications having a selected shape

ABSTRACT

A plurality of flakes are provided that can be used in ink or paint wherein the flakes are of a size that requires magnification to see their shape. The flakes are in the form of regular polygons, such as squares, triangle or rectangles. A breaking or grinding process is used to break a foil into these shaped flakes and frames or walls are provided within the foil sheet so as to delineate the shapes and these lines provided by frames or walls will facilitate breakage in a preferred manner such that the flakes break into selected shaped polygons. Due to the breakage or grinding process, small remnants are typically still present on the shaped flakes as a result of the way in which the foil and flakes are broken, however with magnification, one can see the resultant regular polygonal shape. To clearly see the remnants one requires increased magnification and the remnant itself provides a type of signature. It can be seen as a taggent within a taggent.

CROSS-REFERENCE TO RELATED APPLICATIONS

The present application is a continuation-in-part of commonly owned,co-pending U.S. patent application Ser. No. 11/931,816 filed Oct. 31,2007 which is a continuation-in-part U.S. patent application Ser. No.11/243,122 filed Oct. 4, 2005, now issued U.S. Pat. No. 7,645,510, whichclaims priority from U.S. Patent Application No. 60/696,593 filed Jul.5, 2005, and is a continuation-in-part of U.S. patent application Ser.No. 10/762,158 filed Jan. 20, 2004, now issued U.S. Pat. No. 7,241,489,which is a continuation-in-part of U.S. patent application Ser. No.10/641,695, filed Aug. 14, 2003, now issued U.S. Pat. No. 7,258,915, andwhich is also a continuation-in-part of U.S. patent application Ser. No.10/243,111 filed Sep. 13, 2002, now issued U.S. Pat. No. 6,902,807, thedisclosures of which are hereby incorporated in their entirety for allpurposes.

The present application is a continuation-in-part of commonly owned,co-pending U.S. patent application Ser. No. 12/463,114 filed May 8,2009, claims priority from U.S. provisional patent application No.61/051,463 filed May 8, 2008, and is a continuation-in-part of U.S.patent application Ser. No. 11/243,122 filed Oct. 4, 2005, now issuedU.S. Pat. No. 7,645,510, which claims priority from U.S. PatentApplication No. 60/696,593 filed Jul. 5, 2005, and is acontinuation-in-part of U.S. patent application Ser. No. 10/762,158filed Jan. 20, 2004, now issued U.S. Pat. No. 7,241,489, which is acontinuation-in-part of U.S. patent application Ser. No. 10/641,695filed Aug. 14, 2003, now issued U.S. Pat. No. 7,258,915, and also is acontinuation-in-part of U.S. patent application Ser. No. 10/243,111filed Sep. 13, 2002, now issued U.S. Pat. No. 6,902,807, the disclosuresof which are incorporated herein by reference for all purposes.

The present application is a continuation-in-part of commonly owned,co-pending U.S. patent application Ser. No. 12/938,304 filed Nov. 2,2010, which claims priority from U.S. Provisional Patent Application No.61/257,664 filed Nov. 3, 2009, which are incorporated herein byreference for all purposes.

The present application is a continuation-in-part of commonly owned,co-pending U.S. patent application Ser. No. 12/378,371 filed Feb. 13,2009, which claims priority from U.S. Patent Application No. 61/028,442filed Feb. 13, 2008, which are incorporated herein by reference for allpurposes.

FIELD OF THE INVENTION

The present invention relates generally to thin-film pigment flakeshaving one or more layers, and more particularly to the manufacture ofshaped taggent flakes having a predetermined selected shape for use in acoating composition.

BACKGROUND OF THE INVENTION

Specialty pigments have been developed for use in security applications,such as anti-counterfeiting devices printed on banknotes, packaging ofhigh-value items, seals for containers, and even for direct applicationto commercial items. For example, the U.S. twenty-dollar Federal ReserveNote currently uses optically variable ink. The number “20” printed inthe lower-right corner of the face of the note changes color as theviewing angle changes. This is an overt anti-counterfeiting device. Thecolor-shifting effect is not reproducible by ordinary colorphotocopiers, and someone receiving a note can observe whether it hasthe color-shifting security feature to determine the note'sauthenticity.

Other high-value documents and objects use similar measures. Forexample, iridescent pigments or diffractive pigments are used in paintsand inks that are applied directly to an article, such as a stockcertificate, passport, original product packaging, or to seals that areapplied to an article. Security features that are more difficult tocounterfeit are desirable as counterfeiters continue to become moresophisticated.

One anti-counterfeiting approach uses microscopic symbols on multi-layercolor-shifting pigment flakes. The symbols are formed on at least one ofthe layers of the multi-layer color-shifting pigment flakes by a localchange of an optical property(s), such as reflectivity. The multi-layercolor-shifting pigment flakes generally include a Fabry Perot-typestructure having an absorbing layer separated from a reflective layer bya spacer layer. The reflective layer is typically a layer of metal,which renders the pigment flake essentially opaque. If a large portionof these types of pigment flakes are mixed with other pigment, theresultant color might be significantly different from the pigment, andif too few of these flakes are mixed with other pigment, they might bedifficult to find.

Another technique uses epoxy-encapsulated shaped flakes of polyethyleneterephthalate (“PET”). A reflective layer is deposited on a roll of PET,and then the PET is cut into pieces. The flakes are coated orencapsulated with epoxy to improve the durability of the reflectivelayer. These flakes are available in a variety of shapes, such assquare, rectangle, hexagon, and “apostrophe,” and a selection ofreflective metallic tints, such as silver, pewter, gold, and copper.However, the epoxy layer and the relatively thick PET substrate (whichtypically has a minimum thickness of about 13 microns (0.5 mils) for usein vacuum deposition processes) result in a relatively thick flake,typically greater than 14 microns. Unfortunately, such a thick flake isnot desirable for use in covert applications where the thickness issubstantially greater than the base pigment. Similarly, such thickflakes do not flow well in inks, and create lumps in paint. When paintincludes a thick flake that creates a rough surface, a relatively thickclear topcoat is typically applied over the rough surface.

It is desirable to mark objects with covert anti-counterfeiting devicesthat overcome the limitations of the techniques discussed above.

One aspect of this invention relates to providing polygonal shapedflakes wherein a plurality of flakes has a same shape. For example itwould be desired to have flakes that are regular polygon shaped flakes,such as square shaped, rectangular shaped or triangular shaped. Aparticularly important aspect would be to have flakes with approximatelythe same shape. For example, such that a plurality of flakes could berecognized as square-shaped even though actual edges may differ slightlyfrom the breaking process under which they are formed. In a mostpreferred embodiment of the invention, a plurality of flakes are formedby breaking or grinding a substrate into regular polygon shaped flakes,where all sides are of a substantially equal length and all anglesforming the regular polygon are substantially equal.

Another aspect of this invention relates to providing flakes which havetaggents or covert symbols stamped or embossed or etched therein bymechanical means or formed by laser means, wherein the covert symbolscan be seen with a microscope. In order to preserve the integrity of thesymbols, a frame is provided around all of or part of covert symbols sothat when the individual flakes are removed from the support structurethey are deposited on, the majority of flakes break along the framelines provided instead of breaking in a less controlled unpredictablemanner wherein break lines would otherwise occur with greater frequencythrough and about the symbols. In some instances parallel frame linesmay be provided so that the flakes break into a ribbon; in a preferredembodiment of this invention, flakes and more particularly one or moresymbols within a flake will have a framed grooved border on four orfewer sides about the one or more symbols, so that the flakes break inuniform squares or rectangles along the frame lines. Of coursetriangular or hexagonal flakes may be provided as well in this manner,by pre-framing symbols on three sides, prior to removing the flakes fromtheir backing. A conventional release layer is provided so that theflakes can easily be removed from their backing or support layer and sothat upon removal, the flakes break up along the faming lines. Framescan be made in a similar manner in which the symbols are made; using alaser, etching or stamping of the film that is upon the substrate; in apreferred embodiment, the frames are provided in the same process alongwith the formation of the symbols.

When flakes break into random shapes rather than into a regular polygonof a selected shape, the indicia can be damaged by way of the flakebreaking along or through the indicia. This is shown in FIG. 6 and FIG.8a of EP 0978373 in the name of Muller et al.

Although it may be possible to fabricate flakes in great quantities bycutting a substrate into flakes by use of mechanical cutters, it ispreferred to have a method for fabricating shaped optical effect orpigment flakes, which is less costly and labour intensive by breakingthe flakes along predetermined formed lines. The substrate prior tobeing crushed or broken has delineations therein which are visible andwhich facilitate the breakage of the flakes along predetermined lines.

It is a further object of this invention, to provide shaped flakes whichmay have symbols thereon, and wherein the symbols have or had, frames orborders embossed, or etched into the flake or formed with a laser beamfor protecting the symbols during the process of separating flakes fromtheir temporary support backing.

In one aspect, this invention relates to a method of producing flakeshaving covert symbols therein, wherein convert symbols within the flakesare substantially preserved in the process of removing the flakes fromtheir temporary support backing.

SUMMARY OF THE INVENTION

In accordance with this invention a plurality of shaped covert flakesare provided which may carry a symbol or indicia thereon which cannot beseen without magnification. As a result of the way in which the flakesare broken or ground so as to provide preferred shaped flakes, remnantsof frames, or walls are present due to breaking up the foil intoindividual flakes. By using this method and by providing a structurearound the flake region such as a frame or border, there also existsenough control so that the flakes have predetermined polygon shapes. Ofcourse these remnants are evidence of a coarse breaking or grindingprocess however, the cost benefit of producing flakes in this mannerover the resultant remants being present makes this process desirablecommercially. It is not necessary that flakes edges be absolutelystraight lines without these small remnants. After all, the shape ofthese very small flakes can only be seen with adequate magnification andtherefore these jagged remnants which comprise a very small percentageof the flake are barely noticeable with just enough magnification todiscern the shape of the flake.

In accordance with this invention a plurality of shaped flakes areprovided, wherein each flake has a same general polygonal shape, eachflake having a thickness greater or equal to 0.01 and less than or equalto 10 microns, and wherein each flake has a remnant in the form of aprotruding wall segment on one side of each of the flake wherein theremnant is result of breaking or grinding to form the shaped flakes, andwherein a width of the remnant is less than 20% of a major dimension ofthe flake so that the general polygonal shape of each flake isdistinguishable.

In accordance with another aspect of the invention, a method is providedfor producing flakes having indicia thereon, the method comprising thesteps of: providing a substrate coated with a release layer; providingan optical coating of one or more layers upon the release layer;inscribing indicia in the form of one or more symbols in a plurality ofregions upon the optical coating; inscribing a frame about the indicia,in each region; removing the optical coating from the release layer suchthat the coating is broken into flakes in the form framed indicia.

In yet another aspect of the invention, flakes are provided which haveat least one symbol thereon, wherein the flakes were separated fromadjacent flakes by separating along frames or borders etched, lasered orembossed into the sheet prior to their removal.

In accordance with this invention, there is provided, a foil comprisinga substrate having a releasable material deposited thereon in the formof one or more thin film layers for forming flakes once removed from thesubstrate, the one or more thin film layers having a plurality ofsymbols formed therein at least some of the symbols having framessurrounding the symbols.

In accordance with another aspect of the invention, there is provided, acoating composition comprising: a carrier; and a plurality ofsingle-layer inorganic dielectric covert taggent flakes dispersed in thecarrier, wherein the flakes have indicia thereon are surrounded by aframe.

In accordance with the invention there is further provided, a pluralityof covert flakes having frames about indicia disposed on each flake forproviding lines about which the flakes will break upon removal from asubstrate onto which they were backed.

A coating composition includes covert opaque flakes less than about 10microns thick with identifying indicia. Examples of identifying indiciainclude selected flake shape(s) and/or compositions. The covert flakesare typically dispersed in a carrier, such as a varnish base, paintvehicle or ink vehicle, to form a coating composition. The covert flakesare dispersed in sufficiently dilute concentration so that the covertflakes are not easily detectable in the coating composition by casualobservation and are colored to match the color of a base pigment or havea different optical characteristic, such as being highly reflective(“bright” or “silver”). The shapes of selectively shaped covert flakesare not discerned by unaided human vision, but can be seen under about50× to 300× magnification. In one embodiment, the covert flakes appearto be essentially identical to base pigment flakes in the composition,but are made of different thin-film layers that are detectable usingstandard analytical methods.

In a particular embodiment the covert flakes are a single layer of ashaped inorganic dielectric material, such as ZnS. The thickness of thesingle layer of inorganic dielectric material is selected to provide acovert flake that has color to match mica-based nacreous base pigment.

A composition according to an embodiment of the present invention isapplied to an object to provide a covert security feature. A pigmentedcomposition may be used to print a field (e.g. an image) on the object,and a varnish composition with a low concentration of opaque securityflakes may be used to overprint an existing image on the object. In anembodiment of the invention, covert flake is mixed with base pigment toprovide a covert security feature to images printed with the compositionthat look substantially similar to images printed with only the basepigment.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a plan view of a portion of a document with a security featureaccording to an embodiment of the present invention.

FIG. 2A is a simplified view of a portion of a deposition substratehaving an embossed portion and a non-embossed portion.

FIG. 2B is a simplified view of a portion of another depositionsubstrate 11′ having an embossed portion 13′ and a non-embossed portion15′

FIG. 3A is a simplified plan view of a portion 14A of the securityfeature 14 shown in FIG. 1.

FIG. 3B is a simplified cross section of a bright pigment flake 20according to an embodiment of the present invention.

FIG. 3C is a simplified cross section of a bright flake 20′ providing anelemental fingerprint.

FIG. 3D is a simplified cross section of a color-shifting pigment flake30 according to another embodiment of the present invention.

FIG. 4 is a cross section of a varnish with opaque covert flakesdispersed in a carrier according to an embodiment of the presentinvention.

FIG. 5 is a cross section of base flakes and opaque covert flakesdispersed in a binder according to another embodiment of the presentinvention.

FIG. 6 is a flow chart of a method of making pigment flake according toan embodiment of the present invention.

FIG. 7 is a photograph of a sheet bearing a plurality of Euro symbolseach framed by a square frame or border embossed into the substrate.

FIG. 8 is a photograph of a plurality of Mg-Gn color shifting flakeseach bearing the Euro symbol and most having a full or partial framesurrounding the symbol.

FIG. 9 is a photograph of a plurality of Mg-Gn μ symbols on flakeswherein the flakes have broken randomly preserving some symbols anddestroying others due to the fracture lines as a result of the absenceof frames.

FIG. 10 is a photograph of a plurality of framed symbols within agreater number of flakes absent any covert symbols or frames where aratio of framed symbols to other flakes is 1:10.

FIG. 11 is a photograph of a plurality of μ symbols some of which arecracked through the symbols and some of which have plural symbols on asingle flake; the great distribution in particle size is evidenced herein this photograph due to the absence of providing frames or bordersabout the symbols.

FIG. 12 is an embodiment in accordance with this invention wherein aflake has color shifting properties, magnetic properties, and bears acovert feature within the flake.

FIG. 13 is a photograph of security features wherein covert flakes arealigned to provide an overt security feature bearing the covert featurewithin flakes.

FIGS. 14 a and 14 b are micro-photographs of a cross section of a flakehaving a frame with a thinner cross-section in one region as shown.

FIGS. 15 a, 15 b and 15 c are illustrations of flakes having differentforms of remnants on more than on edge as a result of a breaking orgrinding process.

DETAILED DESCRIPTION OF THE INVENTION I. Introduction

Flakes for covert security applications are not typically seen by casualobservation. Some sort of inspection technique, such as inspection undera microscope or analytical technique, such as elemental analysis, isused. In one embodiment, opaque flakes containing indicia, such as aparticular shape, substantially match the visual characteristics of abulk pigment or other substance they are mixed with. In a particularembodiment, a single-layer inorganic opaque flake having a selectedshape is mixed with an iridescent mica-based flake or other basepigment. For the purpose of this discussion, a “single layer” ofinorganic material includes multiple layers of the same inorganicmaterial built up upon each other.

Inorganic covert flakes are particularly desirable in applications whereheat, solvents, sunlight, or other factors may degrade organic flakes.For example, an inorganic covert flake used in an explosive isdetectable even after exposure to high temperatures and/or pressures,and is persistent in the environment. Flakes according to embodiments ofthe present invention also are substantially thinner, typically lessthan about 10 microns, than conventional shaped flakes, enabling theiruse in ink and produce a smooth surface finish in paints without havingto use a clear topcoat. Thin, inorganic flakes according to embodimentsof the present invention also have a density closer to the density ofbase pigment flakes made using similar techniques. Thick flakesincorporating organic substrates often have a different density thanthin-film base pigment flake, and may segregate, either before or duringapplication while the carrier is fluid. Flake segregation is undesirablebecause it can result in an inconsistent ratio of covert and base flakesin a composition, and may degrade the covert nature of the covert flakesif segregation results in an unduly high concentration of covert flakes.

II. Exemplary Opaque Flake

FIG. 1 is a plan view of a portion of a document 10 with a securityfeature 12 according to an embodiment of the present invention. At leasta portion 14 of the security feature 12 is printed with ink or paintincluding opaque flakes having indicia (hereinafter “covert flakes”)mixed with bulk pigment, such as bulk pigment flakes. In one embodiment,the covert flakes have a particular shape, such as being square,rectangular, trapezoidal, “diamond” shaped, or round, for example. Inanother embodiment, the covert flakes include a grating pattern, with orwithout having a selected shape. Preferably, the selected shape isprovided by embossing, etching or using a laser to create frames orborders along which the flakes will facture upon removal from theirtemporary supporting substrate. In a particular embodiment, the gratingpattern has a grating spacing that is not optically active in thevisible range of the spectrum. That is, these grating patterns do notform a visible diffraction grating. Covert flakes are also sometimesreferred to as taggent flakes, although not all taggent flakes arenecessarily covert flakes.

Generally, bulk pigment particles, including bulk pigment flakes, havean irregular or random shape. In one embodiment, the covert flakes aredistinguishable from bulk pigment flakes by their shape. Alternatively,bulk pigment flakes have a first selected shape, and the covert flakeshave a second selected shape. Production of shaped pigment flakes isaccomplished by a variety of techniques, such as using a patternedsubstrate to deposit the flake material on the substrate and thenseparating the flake from the substrate to obtain the pattern such as aframe or border. The selected shape of the covert flakes may beassociated with a manufacturing facility, date of manufacture, or otheraspect of the document 10, or ink used in producing the document, forexample.

A roll coater is one type of apparatus that can be used to produceselectively shaped or randomly shaped covert flakes according toembodiments of the invention. A roll of a sheet of polymer substratematerial (also known as a “web”) is passed through a deposition zone(s)and coated with one or more thin film layers. Multiple passes of theroll of polymer substrate back and forth through the deposition zone(s)may be made. The thin film layer(s) is then separated from the polymersubstrate and processed into flake. Other apparatus and techniques maybe used.

It is generally desirable to limit the total thickness of thin filmlayers deposited (and hence removed) from a roll of polymer filmsubstrate to less than about 10 microns. PET is one type of polymer filmsubstrate used in roll coaters, and the PET film substrate is usually atleast about 13 microns thick. Thinner PET film tends to thermally deformduring vacuum deposition processes. Both the heat in the deposition zoneand the heat of condensation of the deposited thin-film layer(s)increase the temperature of the polymer substrate as it passes through adeposition zone. Thus, the minimum thickness of flake cut from andincorporating PET film is about 13 microns.

In addition to, flakes having a selected shape preferably realized byembossing frames into the substrate, along which the flakes willseparate and break apart, the covert flakes preferably include a one ormore symbols, other forms of indicia within and bordered by the frames,and/or a grating pattern. The grating pattern is embossed on a substrateused in a roll coater prior to depositing thin film layers that areprocessed into flakes, or otherwise formed. In a further embodiment, aselected amount (percentage) of the deposition substrate surface area isembossed with a grating pattern or shape pattern to obtain a selectedamount of covert flakes when the thin film layers are stripped from thedeposition substrate and processed into flakes. This technique providescovert flakes with the same optical design (thin film layer compositionand thickness) as the base flake. For example, embossing 10% of thedeposition substrate surface area with a grating pattern and/or shapepattern would result in a pigment mixture having about 10% covert flakesas is shown in FIG. 10. Different rolls of deposition substrate areproduced with different percentages of embossed surface area to obtainpigment mixtures having different amounts covert flake, or are embossedwith different patterns to obtain different shapes and/or gratingpatterns.

FIG. 2A is a simplified view of a portion of a deposition substrate 11having an embossed portion 13 and a non-embossed portion 15. Theembossed portion has a frame, which is exaggerated for purposes ofillustration, and alternatively or optionally has a grating or symbol,for example, and the non-embossed portion is essentially smooth.Alternatively, the non-embossed portion is embossed with a differentframe, grating, or symbol. The ratio of the surface area of the embossedportion 13 to the non-embossed portion 15 produces a selected amount oftaggent flake (produced from the embossed portion) having the samethin-film structure as the base flake (produced from the non-embossedportion). The deposition substrate 11 travels from one roll 17 toanother 19 through a deposition zone (not shown) in a roll coater, butalternative embodiments use different types of substrates and depositionsystems. FIG. 2B is a simplified view of a portion of another depositionsubstrate 11′ having an embossed portion 13′ and a non-embossed portion15′.

A pigment flake with identifying indicia provides a security featureeven if it is easily observable; however, if a pigment flake withidentifying indicia is not easily observable, a counterfeiter might noteven be aware that a covert flake is present. One embodiment of thepresent invention uses covert pigment flake that has the same opticalcharacteristics as the base pigment. The covert pigment flakes are notseen by unaided human vision, but are visible under magnification ofabout 50× to 300×. Covert pigment flakes having essentially the samevisual characteristics can be mixed with base pigment in a wide range ofproportions without significantly affecting the color of thecomposition. In some embodiments, covert pigment flakes are readilyidentifiable in compositions having 5-10 weight % covert pigment flakesand 95-90 weight % base pigment flakes having similar appearance (e.g.color and/or color travel). Often, shaped opaque covert flakes areeasily identifiable in the field using hand-held microscopes (e.g.“shirt-pocket” microscopes), and require less magnification to identifythan similar sized flakes having symbols.

Another approach is to use an opaque covert flake with a selected shapethat is a different color than the base flake. In one embodiment, theopaque covert flake is a bright metallic (“silver”) flake having athin-film layer of aluminum or other reflector between layers of adielectric material, such as MgF₂. Bright flake is generally highlyreflective over a wide range of visible wavelengths, and often does nothave a characteristic color. Bright flake made with gold and copper mayappear yellowish and reddish, for example. It has been found thatbetween about 0.25 weight % to about 5 weight % of shaped (e.g.“diamond” shaped) bright flake in colored base pigments can be addedwithout causing a noticeable change in color, but are still easilyidentifiable under illuminated magnification of about 50× (i.e. 50 timesmagnification). Under illuminated magnification, both the shape and highbrightness of the flake distinguish it from the base flake. When lessthan about 0.25% of shaped bright flake is used the covert flakes becomedifficult to detect because dilution with the base flake results infewer shaped bright flakes in the field of view.

When the amount of bright flake exceeds about 5 weight %, the color(e.g. hue) of certain types of flakes, particularly dark colored flakes,changes. In these instances, too much bright flake essentially “dilutes”the color of the base pigment. However, using shaped bright flake incompositions having color-shifting pigment is highly desirable because asingle type of shaped bright flake is added in small quantities to manydifferent types (color and/or color travel) of pigment flake, and arelatively small amount of shaped bright flake provides a covertsecurity feature. Similarly, dilution of color is not critical inapplications where compositions containing pigment and bright flake arenot intended to replace or otherwise be indistinguishable fromcompositions containing 100% pigment flake.

Pigments are often mixed in carriers to form paint or ink Examples ofcarriers include polyvinyl alcohol, polyvinyl acetatepolyvinylpyrrolidone, poly(ethoxyethylene), poly(methoxyethylene),poly(acrylic) acid, poly(acrylamide), poly(oxyethylene), poly(maleicanhydride), hydroxyethyl cellulose, cellulose acetate, poly(sacchrides)such as gum arabic and pectin, poly(acetals) such as polyvinylbutyral,poly(vinyl halides) such as polyvinyl chloride and polyvinylenechloride, poly(dienes) such as polybutadiene, poly(alkenes) such aspolyethylene, poly(acrylates) such as polymethyl acrylate,poly(methacrylates) such as poly methylmethacrylate, poly(carbonates)such as poly(oxycarbonyl oxyhexamethylene, poly(esters) such aspolyethylene terephthalate, poly(urethanes), poly(siloxanes),poly(suphides), poly(sulphones), poly(vinylnitriles),poly(acrylonitriles), poly(styrene), poly(phenylenes) such aspoly(2,5dihydroxy-1,4-phenyleneethylene), poly(amides), natural rubbers,formaldahyde resins, other polymers and mixtures of polymers andpolymers with solvents.

FIG. 3A is a simplified plan view of a portion 14A of the securityfeature 14 shown in FIG. 1. The portion 14A of the security feature isviewed under magnification, typically about 20×-300×, in order to seethe shape of the flakes, which are typically about 5-100 microns across,more typically about 20-40 microns across. The security feature wasprinted using ink including base pigment particles 16 and a covertpigment flake 18 having a selected shape, in this case a “diamond”shape. The optical characteristics and concentration of the covertpigment flake is chosen so as to not disturb the visual appearance of acomposition made with the base pigment particles.

The base pigment particles 16 are illustrated as being irregularlyshaped flakes. Alternatively, base pigment flakes have a selected (i.e.regular) shape. Similarly, the covert pigment flake 18 could have agrating. The addition of a grating further increases the difficulty ofcounterfeiting. In some embodiments, the covert pigment flake 18 hasgenerally the same optical characteristics as the base pigmentparticles. Alternatively, the covert pigment flake 18 has differentoptical characteristics as the base pigment particles but is present insufficiently small quantities so as not to disturb the visual appearanceof a composition made with the base pigment particles.

In a particular embodiment, the “diamond-shaped” covert flakes werebright flakes about 25 microns by 35 microns across. The shaped flakeswere made by embossing a diamond pattern into a roll of PET depositionsubstrate material, and then depositing a standard thin-film design forbright flake (e.g. about 100-60 nm of Al between layers of MgF₂ that areeach about 400 nm thick). The total thickness for this bright flake isabout 900 nm, which is about one micron. The embossed pattern is alsoknown as a “frame” (as opposed to a grating which is intended to producea pattern in or on the flake), and is positive in some embodiments andnegative in other embodiments. Aside from the diamond flakes themselvesoffering some measure of a covert feature when distributed in somepredetermined ratio with other irregular shaped flakes, thediamond-shaped flakes may be embossed with additional covert symbols,thereby providing two levels of covert features available to protect adevice.

The combination of a metal layer with one or more dielectric layersfacilitates removal of the flake from the deposition substrate. A thinfilm stack having only dielectric layers is brittle and often hasresidual stresses from the deposition process. Such thin film stackstend to break more randomly, resulting in fewer shaped flakes. Anall-metal stack or single layer is difficult to process into patternedflakes according to the frame of the deposition substrate because themetal is relatively ductile. In particular embodiments, metal-dielectricand dielectric-metal-dielectric flake having a total thickness ofbetween about 0.5 microns and about 3 microns provides a goodcombination of ductile and brittle characteristics that result in goodpatterning of the flake when it is removed from the substrate andprocessed. In a particular embodiment, shaped bright flake having atotal thickness of about one micron of a ductile metal layer betweenbrittle dielectric layers yielded about 90% diamond-shaped flakes froman embossed deposition substrate.

The thin-film layers were stripped from the deposition substrate andprocessed into flake using conventional techniques. The embossed diamondpattern provided lines along which the thin-film layers broke intoflakes having the selected diamond shape. In another embodiment, thediamond-shaped flakes were about 12 microns by 16 microns and included agrating on the major surface of the flakes. The grating was nominally2000 lines/mm and did not produce a noticeable diffractive effect in acomposition when used as a taggent. The shape of the 12-by-16 micronflake was easily seen at 100× magnification; however, the grating wasnot easily seen at this magnification. The grating was readily apparentat 400× magnification. In other embodiments, a grating is coarser, andis easily seen at the same magnification (e.g. 50× to 100×) that is usedto discern the shape of the taggent flakes. Thus, gratings used toprovide a security feature to taggent flakes do not have to be opticallyactive in the visible portion of the spectrum.

In a particular embodiment, the base pigment particles are flakes ofmica coated with a layer of TiO₂ or other dielectric material. Thecoating material typically has a relatively high index of refraction.Mica is a naturally occurring mineral that is relatively inexpensive andeasily processed into flake substrate. When mica flake substrate iscoated with a layer of high-index material of a selected thickness, anacreous pigment flake is obtained. Mica flake substrate can be coatedwith several alternative materials using a variety of processes. Suchpigments are commonly known as “mica-based” pigments. A photocopy of animage printed with such nacreous pigment does not look like theoriginal, thus mica-based pigment flakes are desirable for use toprovide overt security features. However, shaping mica flake substrateor providing a symbol on mica flake substrate is impractical. Covertflake according to an embodiment of the present invention is mixed withthe mica-based pigment to enable a covert security feature to beincluded in images printed with mica-based pigment flakes. Shapedpigment flakes made of a single layer of inorganic dielectric material,such as TiO₂ or ZnS, have an appearance similar to a mica-based pigmentif the covert pigment flake has a thickness about five times thequarter-wave optical thickness (“QWOT”) at a wavelength in the visiblespectrum. Typically, a single-layer covert flake of ZnS intended tomatch the appearance of a mica-based pigment has a thickness of about 60nm to about 600 nm. Processing all-dielectric flake from a depositionsubstrate having an embossed diamond-shaped pattern tends to have alower yield than a counterpart metal-dielectric flake.

FIG. 3B is a simplified cross section of a bright pigment flake 20according to an embodiment of the present invention. A reflective layer22 is between two dielectric thin-film layers 24, 26. The dielectricthin-film layers 24, 26, provide stiffness to the bright pigment flake20 and facilitate removal of the pigment flake from the roll coatersubstrate. It is desirable to keep the bright pigment flake less than 10microns thick to provide a composition that dries or cures to a smoothsurface. In particular embodiments, the thickness of the flake isbetween about 1 micron and about 3 microns. Thinner flakes tend to bemore difficult to process and handle because they weigh so little, andthicker flakes are stronger, and hence more difficult to break along theframe pattern.

The reflective layer 22 is typically a thin-film layer of a highlyreflective metal such as aluminum, platinum, gold, silver, or copper, ora moderately reflective metal, such as iron or chromium. The reflectivelayer 22 is sufficiently thick to be opaque (reflective) in the visibleportion of the spectrum, but not so thick as to interfere withseparation of the thin-film layers from the substrate and subsequentprocessing into flake. In other words, a metal reflective layer that wastoo thick would provide a ductile layer between the relatively brittledielectric layers 24, 26 and tend to interfere with processing thedeposited layers into flakes. Suitable materials for the dielectriclayers include ZnS, MgF₂, SiO₂, Al₂O₃, TiO₂, Nb₂O₅, and Ta₂O₅, amongothers. In some embodiments, the dielectric thin-film layers 24, 26 alsoprovide environmental protection for the reflective layer 22.

The bright flake 20 has a selected shape, and optionally oralternatively has other indicia, such as a surface (grating) pattern oran elemental fingerprint. In sufficiently low concentrations, the brightflake 20 is added to colored pigment and colored compositions (e.g. inksand paints). Shaped bright flake can be added to base (i.e. randomlyshaped or alternatively shaped) bright flake as a covert securityfeature.

FIG. 3C is a simplified cross section of a bright flake 20′ with anelemental indicator layer 28. The bright flake 20′ has reflective layers22′, 22″ between dielectric layers 24′, 26′, and a layer 28 providing anelemental indicator. The elemental indicator layer 28 is a layer ofmaterial that is not found in a base pigment that the bright flake willbe used with, and that is readily detectable using elemental analysistechniques, such as secondary ion mass spectrometry (“SIMS”), energydispersive X-ray (“EDX”) and Auger analysis. Furthermore, the elementalindicator is present in the covert flake but not in the base flake, andmicro-SIMS, micro-EDX or micro-Auger analysis easily detects thisdifference. Merely adding the indicating element to the pigment mixture(e.g. adding a small amount of a compound containing the indicatingelement to the carrier) would not overcome this security feature.

The elemental indicator layer 28 is not optically active because it isbetween the two opaque reflective layers 22′, 22″. The reflective layers22′, 22″ are selected to be of the same material used in the base flake,such as aluminum. Suitable materials for an elemental indicator includeplatinum, iridium, osmium, vanadium, cobalt, and tungsten, among others.Those of skill in the art appreciate that the elemental indicatormaterial chosen depends on the base pigment it will be used with. In analternative embodiment, the reflective layer of bright pigment is of anelemental indicator material (see FIG. 3B, ref. num. 22). For example,covert bright or colored pigment flake using platinum as the reflectivelayer is mixed with base bright flake or colored pigment flake usingaluminum as the reflective layer. In a further embodiment, the amount offlake having the elemental indicator incorporated into a pigment mixtureor composition is chosen to provide a selected elemental ratio (e.g.aluminum to platinum) in the pigment mixture. In an alternative orfurther embodiment, the material of the dielectric thin-film layers 24′,26′ (FIG. 3B, ref. nums. 24, 26) is chosen to provide an elementalindicator.

FIG. 3D is a simplified cross section of a color-shifting pigment flake30 according to another embodiment of the present invention. Thecolor-shifting pigment flake 30 is generally known as a symmetrical5-layer Fabry-Perot interference flake. A thin film stack 32 includes areflective metal layer 34, two spacer layers 36A, 36B, and two absorberlayers 38A, 38B. The absorber layers are typically very thin,semi-opaque layers of chromium, carbon, or other material. Thereflector, spacer, and absorber layers are all optically active, thatis, they contribute to the optical performance of the color-shiftingpigment flake. Each side of the flake provides similar Fabry-Perotinterference structures to incident light, and hence the flake isoptically symmetrical. Alternatively, the color-shifting pigment flakeis an all-dielectric pigment flake or a 3 layer flake such as anabsorber/dielectric/absorber.

The color and color travel of the color-shifting pigment flake isdetermined by the optical design of the flake, namely the material andthicknesses of the layers in the thin film stack 32, as is well-known inthe art of optically variable pigments. The optical design of thecolor-shifting pigment flake 30 is typically chosen to match the opticalproperties of the base pigment flake that it will be mixed with. Thecolor-shifting pigment flake 30 is shaped (see FIG. 3A, ref. num. 18),and optionally or alternatively includes other indicia, such as asurface grating pattern and/or elemental indicator.

For example, the reflective layer includes an elemental indicator,either a reflective metal that is different than the base pigmentflakes, or includes an additional elemental indicator layer(s), whichmay or may not be optically active (see FIG. 3C, ref. num. 28).Alternatively or additionally, the spacer layers 36A, 36B and/or theabsorber layers 38A, 38B include an elemental indicator. For example, ifthe base pigment flake uses MgF₂, SiO₂, or Al₂O₃ as a spacer layermaterial, the covert pigment flake 30 uses different spacer layermaterial, such as TiO₂ or ZnS. Spacer and/or absorber indicatormaterials include elements that are easily detected using elementalanalysis.

In some embodiments, using a different spacer material and/or reflectormaterial results in a covert pigment flake 30 that has different opticalproperties than the base flake. For example, even if the covert and baseflakes have similar color at normal incidence, the color travel might bedifferent. Generally, low-index spacer materials (such as MgF₂ and SiO₂)provide more color travel (“fast shifting” pigments) than high-indexspacer materials (such as ZnS and TiO₂). However, such covert flakes canbe added in relatively high concentrations to the base pigment flake,even if the color travel does not precisely match that of the baseflake, because most casual observers cannot detect the differencebetween a mixture according to an embodiment of the invention and 100%base flake.

FIG. 4 is a cross section of a varnish 40 with covert flakes 42dispersed in a carrier 44 according to an embodiment of the presentinvention. The carrier is clear or tinted, and the covert flakes 42 areat a concentration selected to avoid casual visual detection. Anoptional color coat or bright (e.g. “chromed”) coating 46 has beenapplied to an object 48 underneath the varnish 40. The varnish 40provides a covert security feature to the object without disturbing itsappearance. In a particular embodiment, the optional color coat 46 is animage printed with nacreous or color-shifting pigment to provide anovert security feature to the object. The object is a document, product,packaging, or seal, for example. The varnish 40 enables providing acovert security feature to an object that already has a covert securityfeature without significantly altering the appearance of the object. Forexample, if stock certificates have been printed with overt securityfeatures and it subsequently becomes desirable to provide a covertsecurity feature to the stock certificates, the overt security featureis over-printed with the varnish 40 or a similar ink composition (i.e.an essentially clear ink composition containing covert flakes). Inanother embodiment, an additional covert security feature is provided toan object already having one or more covert security features. In aparticular embodiment, the covert flakes make up not more than 2% of thevarnish.

FIG. 5 is a cross section of a composition 50 (e.g. ink or paint)including base pigment flakes 16 and shaped covert flakes 18 dispersedin a binder or carrier 52 according to another embodiment of the presentinvention. The covert flakes 18 have a selected shape or other indicia,such as an elemental indicator or a surface grating pattern. Thecomposition 50 has been applied to an object 48, such as a label,product packaging, bank note, or consumer item.

Adding covert flake to an existing ink or paint composition provides acovert security feature to images made of the ink or paint. For example,ink with color-shifting pigment is used to provide a color-shiftingimage as an overt security feature on a bank note or other object.Covert flake according to an embodiment of the present invention isadded to the ink, and the resultant mixture is used to print images thatappear substantially similar as those printed with the original ink.Thus, a casual observer of the bank note does not notice a change in theappearance of the overt security feature (i.e. color-shifting image)after the covert security feature is added. The indicia of the covertflake indicates a date-of-manufacture, a printing location, and/or thesource (manufacturer) of the ink, for example.

III. Experimental Results

A test standard using 100% magenta-to-green optically variable intaglio(“OVI”) pigment flake was produced and measured. Both bright andoptically variable taggent samples had a grating pattern of 2000lines/mm, which made the taggent flakes easier to distinguish from thebase pigment flake (i.e. locate) and more difficult to counterfeit. Thegrating pattern was clearly visible at about 400×, and did not inducevisible diffractive properties to images printed with the testcompositions. It is believed that the low portion of the taggent flakesin combination with not being well oriented to the viewer avoided adiffractive effect from occurring. In an alternative embodiment, a finergrating pattern is included on shaped taggent flakes. The shapes areidentifiable under a microscope at a first magnification, but thegrating pattern is not easily seen at this first magnification. Thegrating pattern is seen at a higher magnification. It is believed thatincluding such a grating pattern to taggent flake having a selectedshape or symbol further enhances the covert nature of the taggent flakebecause a counterfeiter might see the shape or a symbol undermicroscopic examination, but not see the grating pattern, and hence notinclude it in a counterfeit article.

The first test sample (“sample 1”) contained 90% (by weight) of theconventional (base) magenta-to-green pigment flake mixed with 10%magenta-to-green OVI pigment flake with a grating (“taggent flake”). Thetaggent flakes were easy to detect by routine microscopic inspection,and the color performance of the mixture was the same as the teststandard because the color of the taggent flake was well matched to thecolor of the base flake. Close color matching involves carefulmonitoring of the production of the taggent flake and a new opticaldesign for each color of taggent flake would generally be used to matcheach color of base flake.

Another approach is to use a standard taggent flake design that can beused with many different colors of base flake. Bright taggent flakeusing an aluminum reflector layer (giving the flake a “silver”appearance) was also evaluated. Fabrication of bright flake isrelatively simple and these flakes were very easy to detect at aconcentration of 5% when mixed with colored base pigment flakes. Brighttaggent flakes are used with many colors of base pigment to providecovet security features. The amount of bright taggent flakes in thecomposition depends on the desired result. For example, the colorperformance of an intaglio blend containing 5% bright taggent flakemixed with the magenta-to-green OVI base is distinguishable in aside-by-side comparison from a composition of 100% magenta-to-green OVIflake. A composition essentially indistinguishable from 100%magenta-to-green OVI flake uses less than 5% bright flake, such ascompositions with concentrations between about 0.25 weight % and 3weight % of bright taggent flake in magenta-to-green OVI flake. It isbelieved that bright flake in concentrations greater than 5% may beadded to pigment flake providing lighter or less saturated color withoutnoticeably changing the appearance of the composition. Bright taggentflakes are easy to detect under modest magnification, even atconcentrations below 1%, because of the combination of having a selectedshape and of being a different color (e.g. “silver” instead of magenta).

IV. Exemplary Methods

FIG. 6 is a flow chart of a method 600 of making pigment flake accordingto an embodiment of the present invention. A roll substrate having anon-embossed (“smooth”) portion and an embossed portion in a selectedratio of the deposition surface area of the roll substrate is provided(step 602). In one embodiment, the embossed portion is embossed with aframe for producing flakes having a selected shape. In an alternativeembodiment, the embossed portion is embossed with a grating pattern orsymbol. In an alternative embodiment, the substrate is patterned using aprocess other than embossing, such as laser ablation. At least one thinfilm layer is deposited on the roll substrate (step 604), and thedeposited thin film layer(s) is processed into flake (step 606) toresult in a flake mixture having a selected amount of taggent flakes.The yield of taggent flake depends on factors such as the type ofthin-film layers being processed, the nature of the frame, gratingpattern, or symbol, and processing parameters.

For example, referring to FIGS. 2A and 2B, if 10% of the surface of theroll substrate is embossed with a grating or symbol, then a yield ofapproximately 10% taggent flake having the grating pattern or symbol isexpected. If 10% of the surface of the roll substrate is embossed with adiamond-shaped frame, then a yield of about 9% is expected fordielectric-metal-dielectric flake because of the 10% yield lossprocessing the patterned portion of the thin film stack into shapedflakes. Similarly, a yield of about 5% is expected for shapedall-dielectric flake because of the 50% yield loss processing thepatterned portion of the thin film stack into shaped flakes.

While the invention has been described above in terms of variousspecific embodiments, an aspect of the invention which providessignificant advantages will now be described.

For example an embodiment of this invention which offers significantadvantages is the aspect of using frames or borders framing symbols orindicia framed by these borders on a substrate material used to form acoating upon.

Turning now to FIG. 7, a photograph is shown of sheet bearing aplurality of Euro symbols wherein each

symbol on the sheet has an embossed border around it. This is generallyaccomplished by embossing an organic substrate, such as a PET substratewith the framed

symbols, and subsequently coating the substrate with a removablecoating. FIG. 8 is a photograph of the flakes after separation fromtheir backing or substrate. This photograph clearly shows most of thesymbols to be intact with few cracks appearing into or through thesymbols. By using this invention, a very small portion of the flakes inthe figure are broken in such a manner as to obscure the

symbol. However what is shown is that the frames are not present alongall sides of all flakes after the flakes break apart from the substratethey were deposited on. Some flakes have no borders and others may haveone and up to four borders. However, this is understandable. Since aframe border separates the flake from its nearest neighbour, when theflakes separate the border generally remains attached to one flake annot its adjacent flake on the other side of that frame border. Howeverthe existence of the frame or border results in most of the flakesbreaking upon frame lines, on one side of the frame or the otherproviding relatively uniform flakes with relatively straight edges. Moreoften than not, each flake bearing a symbol will have at least oneborder or frame segment attached to it after separating from the web orsubstrate it was deposited on.

FIGS. 7 to 13 were filed in color as part of U.S. Ser. No. 11/243,122filed Oct. 4, 2005, now issued as U.S. Pat. No. 7,645,510, of which thepresent application claims priority.

FIG. 9 is a photograph of a plurality of Mg-Gn flakes bearing μ symbolswherein the flakes have broken randomly preserving some symbols anddestroying others, due to stress cracks and resulting apparently randomfracture lines as a result of the absence of frames. FIG. 9 illustratesstress cracks throughout the flakes causing the flakes to separate as afunction of these cracks. Furthermore, cracks continue to appear withinflakes thereby obscuring symbols. The provision of frames in accordancewith this invention does not entirely prevent stress cracks, howeverprovides a means in which these cracks can be controlled to a greaterextent, so as to occur or be preferentially routed along the framelines. In contrast to FIG. 9, the embodiment of this invention shown inconjunction with FIGS. 7 and 8 offers a manner in which the flakes canbe separated along predetermined borders thereby preserving the shapeand integrity of the symbols on the flakes to a much higher degree andgenerally does obscure the covert symbol within the flake.

The cracks that do appear in the non-framed symbols appear and propagatein the more fragile, glass-like, dielectric material but are stopped andrerouted to continue their propagation along the frame lines provided inthe sheet of framed symbols shown in FIG. 7. The provision of framesproduces the preferential rupture of the flakes along frame lines. Mostof the cracks observed in the flakes of FIG. 8 do not go all the waythrough the total thickness of the flakes, but are stopped at the levelof the more elastic metallic core (Al/Ni/Al) of the flakes producing ashadowing effect detrimental to the readability of the originallyembossed symbols.

The flakes in both FIGS. 8 and 9 are about 1300 nm or 1.3 microns inthickness and have a layer structure of 10 nm Cr/480 nm MgF2/80 nm Al/50nm Ni/80 nm Al 480 nm MgF2/10 nm Cr. Ni is present to provide themagnetic layer for overt features.

Turning now to FIG. 10 is a photograph of a plurality of framed symbolswithin a greater number of flakes absent any covert symbols or frameswhere a ratio of framed symbols to other flakes is 1:10. There are twointeresting aspects of this embodiment. On a first level of detection,one, equipped with a 100× hand held microscope can detect the presenceof covert flakes with a Euro symbol thereon, and furthermore, one canalso quickly approximate that the ratio of covert to non-covert symbolsis about 1:10. Yet still further, one can compare the ratio of squaresymbols to randomly shaped flakes to provide some measure ofauthentication. Therefore, shape, distribution, and identification ofthe symbols within framed shapes can be used to determine if the coatingis authentic within some range of assurance.

FIG. 11 is a close-up detailed photograph of a plurality of μ symbolssome of which are cracked through the symbols and some of which haveplural symbols on a single flake; the great distribution in particlesize is evidenced here in this photograph due to the absence ofproviding frames or borders about the symbols.

FIG. 12 illustrates an embodiment in accordance with this inventionwherein a flake has color shifting properties, magnetic properties, andbears a covert feature within the flake. Preferably the flake is alsobordered by a frame to preserve its shape.

Turning now to FIG. 12, a pigment flake is shown having a magnetic layersandwiched between two aluminum reflective layers. Each of the aluminumlayers in addition to an absorber and dielectric layer provide colorshifting layers on each side. Within the flake is stamped a covert“euro” symbol thereon which can be seen with suitable magnification. Theembodiment shown in FIG. 13 utilizes a plurality of the flakes shown inFIG. 12 to provide a security features that are both covert and overt.

The covert and overt features are illustrated in the photograph which isa compilation of 3 photographs depicted by FIG. 13 where a large Eurosymbol and a map of the continents are shown on the upper right in thephotograph and wherein a globe is shown on the upper left of thephotograph printed by silk screen in the presence of magnetic fields tocreate different visual contrasts (rolling bar effect) in addition tothe standard green to magenta color shifting.

In this instance the covert framed square flakes of about 30 microns insize bear a Euro symbol about 17 microns across.

Of course other optical designs, magnetic or non-magnetic, shapes orsymbols can be created as desired. By using the layer structure of theflake in FIG. 12, optically variable, special magnetically alignable,and covert feature can be provided within a same security device.

By using frames in accordance with the teachings of this invention,particular shapes having preferential side benefits may be utilized. Forexample, if the flakes are rectangular in shape, instead of beingsquare, preferentially orientation of the symbols can be achieved, usingmagnetic shape anisotropy inherent of elongated flakes. Thus byproviding a magnetic layer, for example of Ni, and ensuring that theflakes separate as elongate flakes due to the frames being designed Ithis manner, the flakes can be aligned as a function of their shape, andthe symbols may have a preferential orientation, or be more likely toorient by this process.

Referring now to FIGS. 14 a and 14 b a cross section of a flake having aframe is shown wherein a thinner region with a bend has a thinnercross-section than the rest of the flake. The flake tends to break wherethe cross-section is thinner than the average cross-section of theflake, as this thinner region facilitates breakage.

Thus, the embodiments described above illustrate the invention, but arenot restrictive of the invention, which is indicated by the followingclaims. All modifications and equivalents that come within the meaningand range of the claims are included within their scope.

Although preferred embodiments of the invention relate to pigmentflakes, it is possible to use a non-symmetrical flake having features onone side such as optically variable features. In this instance,approximately half of the flakes when examined will show the covertfeature and other optical features, and the other half will not appearthe same due to a lack of symmetry within a flake. Notwithstanding, thismay still offer a reasonable covert security feature which can be usedto authenticate.

In embodiments of this invention, shaped flakes can be made by othermethods that are similar in one respect to the provision of frames, butwhich provide useful manufacturing alternatives. For example, U.S.patent application Ser. No. 11/931,816 now published U.S. Application20080107856 from which this application claims priority teaches theprovision of forming a substrate or stamping a substrate so as to beframeless but to have walls which facilitate flakes breaking alongpredetermined boundaries. U.S. patent application Ser. No. 12/463,114now published U.S. Application 20090217842 from which this applicationclaims priority teaches the provision of a stamped substrate that has apostage-stamp like embossing that facilitates breakage of the flakealong predetermined boundaries. All of these embodiments have a sameresult which is facilitating flakes to break in predetermined polygonalshapes and we believe the means in which this is done is by providing athinner region along a boundary of flake; for example a frame or a wallor a linear embossing provided facilitates breaking in a controlledmanner along lines of thinner material than other thicker regionsadjacent thereto. When the flakes are broken, each edge will upon highmagnification show evidence of being broken by being somewhat jagged asopposed to a straighter edge that would be produced by cutting. When theflakes of this invention are magnified with sufficient magnification todetermine the shape by visually inspecting the flakes, the selectedshaped flakes are recognizable as being a same selected shape, howeverupon closer inspection and with significantly higher magnification,differences are seen along edges of different flakes, and often evenedges of the same flake vary from one another. Due to the thinning ofthe edge, and forces applied in breaking the flakes, the break lines mayappear slightly jagged or have a cleaved appearance. In almost all casesthere will also be a remnant of a wall remaining.

Referring now to FIG. 15 a substantially planar flakes having at leastone planar side are show, wherein a flake has remnants 150 a of a frameshown along two edges. As was described heretofore, the provisional of aframe facilitates breakage. Notwithstanding, due to the grinding andbreaking process almost all shaped flakes will have some remnants of theframe wall. In FIG. 15 b a remnant 150 b is shown in the form of anupstanding wall that was provided to facilitate breakage of the flakeabout or along the wall edge. In nearly all instances the breakage ofthe coating on the substrate will provide shaped flakes of a preselectedshape, however in most instances there will be one or more remnants of awall along one or more edges of the flake. FIG. 15 c illustrates ashaped flake that was made using the postage-stamp method describedheretofore. Once again, at least a remnant of a wall 150 c is presentalong two edges, as shown. Fortunately, these remnants are so small,that when just enough magnification is used to see the shaped flake,these remnants are barely visible and don't significantly detract fromthe appearance of the shaped flake. Since the remnants are of differentforms, depending on the particular feature provided to facilitatebreakage, one can identify the flakes in accordance with the feature.For example another way in which security is added to the flake, is thatone can identify if it was made by using frames, or walls or the postagestamp like feature to facilitate breakage. These remnants form a type ofrecognizable signature.

1. A plurality of shaped flakes, wherein each flake has a same generalpolygonal shape, each flake having a thickness greater than or equal to0.01 μm and less than or equal to 10 μm, and wherein each flake has aremnant in the form of a protruding wall segment on one side of each ofthe flake wherein the remnant is result of breaking or grinding to formthe shaped flakes, and wherein a width of the remnant is less than 20%of a major dimension of the flake so that the general polygonal shape ofeach flake is distinguishable.
 2. A plurality of shaped flakes asdefined in claim 1, wherein one surface of the flake is substantiallyplanar and wherein another opposite surface of the flake is not entirelyplanar due to the presence of one or more remnants, and wherein theflake is of a size such that the polygonal shape can only be seen withmagnification.
 3. A plurality of shaped flakes as defined in claim 2wherein edges of each of the flakes are jagged as a result of a breakingor grinding process.
 4. A plurality of shaped flakes as defined in claim3 comprising a binder.
 5. A plurality of shaped flakes wherein theshaped flakes as defined in claim 1 wherein the flakes have indiciathereon.
 6. A plurality of shaped flakes as defined in claim 1 wherein aremnant has a width and length in the plane of the flake, and a height.7. A plurality of shaped flakes as defined in claim 1 wherein the shapedflakes comprise bright flakes.
 8. A plurality of shaped flakes of claim7 wherein the shaped flakes have a grating pattern, the selected shapebeing visible at a first magnification and the grating pattern not beingvisible at the first magnification, wherein the grating pattern isvisible at a second magnification, the second magnification beinggreater than the first magnification.
 9. A plurality of shaped flakes ofclaim 1 wherein the shaped flakes include a grating pattern which canonly be seen with magnification.
 10. A plurality of shaped flakes ofclaim 2 wherein the flakes have a reflective layer, a spacer layer, andan absorber layer.
 11. A plurality of shaped flakes as defined in claim1, wherein the shaped flakes include single-layer inorganic dielectrictaggent flakes.
 12. A plurality of shaped flakes wherein the flakes arein the shape of a regular polygon.
 13. A composition comprising aplurality of the shaped flakes as defined in claim 1 and a binder foruse as toner for a laser printer.
 14. A composition comprising aplurality of shaped flakes as defined in claim 1 in an ink for use in aninkjet printer.